CHEMICAL ABUNDANCE
Content: Chemical abundance and evolution, ...Star forming regions,
...QSOs
Abstracts from Annual
Review of Astronomy and Astrophysics and A. McWilliam, E. F. van Dishoeck, Geoffrey A. Blake, Fred Hamann, Gary Ferland et al.
1. ABUNDANCE
RATIOS AND GALACTIC CHEMICAL EVOLUTION
The
metallicity of stars in the Galaxy ranges from [Fe/H] = 4 to +0.5
dex, and the solar iron abundance is (Fe) =
7.51 ± 0.01 dex. The average values of [Fe/H] in the solar
neighborhood, the halo, and Galactic bulge are 0.2, 1.6, and 0.2 dex
respectively.
Detailed
abundance analysis reveals that the Galactic disk, halo, and bulge
exhibit unique abundance patterns of O, Mg, Si, Ca, and Ti and
neutron-capture elements. These signatures show that environment plays
an important role in chemical evolution and that supernovae come in
many flavors with a range of element yields.
The
300-fold dispersion in heavy element abundances of the most metal-poor
stars suggests incomplete mixing of ejecta from individual supernova,
with vastly different yields, in clouds of 106
M.
The
composition of Orion association stars indicates that star-forming
regions are significantly self-enriched on time scales of 80 million
years. The rapid self-enrichment and inhomogeneous chemical evolution
models are required to match observed abundance trends and the
dispersion in the age-metallicity relation.
2. CHEMICAL
EVOLUTION OF STAR-FORMING REGIONS
Recent
advances in the understanding of the chemical processes that occur
during all stages of the formation of stars, from the collapse of
molecular clouds to the assemblage of icy planetesimals in
protoplanetary accretion disks, are reviewed. Observational studies of
the circumstellar material within 10010,000
AU of the young star with (sub)millimeter single-dish telescopes,
millimeter interferometers, and ground-based as well as space-borne
infrared observatories have only become possible within the past few
years. Results are compared with detailed chemical models that
emphasize the coupling of gas-phase and grain-surface chemistry.
Molecules that are particularly sensitive to different routes of
formation and that may be useful in distinguishing between a variety of
environments and histories are outlined. In the cold, low-density
prestellar cores, radicals and long unsaturated carbon chains are
enhanced. During the cold collapse phase, most species freeze out onto
the grains in the high-density inner region. Once young stars ignite,
their surroundings are heated through radiation and/or shocks,
whereupon new chemical characteristics appear. Evaporation of ices
drives a "hot core" chemistry rich in organic molecules, whereas shocks
propagating through the dense envelope release both refractory and
volatile grain material, resulting in prominent SiO, OH, and H2O
emission. The role of future instrumentation in further developing
these chemical and temporal diagnostics is discussed.
3.
ELEMENTAL ABUNDANCES
IN
QUASISTELLAR OBJECTS:
Star Formation and Galactic Nuclear Evolution at High Redshifts
Quasar
(QSO) elemental abundances provide unique probes of high-redshift star
formation and galaxy evolution. There is growing evidence from both the
emission and intrinsic absorption lines that QSO environments have
roughly solar or higher metallicities out to redshifts >4. The range
is not well known, but solar to a few times solar metallicity appears
to be typical. There is also evidence for higher metallicities in more
luminous objects and for generally enhanced N/C and Fe/ abundances compared with solar ratios.
These results identify QSOs with vigorous,
high-redshift star formationconsistent
with the early evolution of massive galactic nuclei or dense
protogalactic clumps. However, the QSOs offer new constraints. For
example, (a) most of the enrichment and star formation must
occur before the QSOs "turn on" or become observable, on time scales of
1 Gyr at least at the highest redshifts. (b)
The tentative result for enhanced Fe/ suggests that the first local star
formation began at least 1 Gyr before the QSO epoch. (c)
The star formation must ultimately be extensive to reach high
metallicities; that is, a substantial fraction of the local gas must be
converted into stars and stellar remnants. The exact fraction depends
on the shape of the initial mass function (IMF). (d) The highest
derived metallicities require IMFs that are weighted slightly more
toward massive stars than in the solar neighborhood. (e) High
metallicities also require deep gravitational potentials. By analogy
with the well-known massmetallicity
relation among low-redshift galaxies, metal-rich QSOs should reside in
galaxies (or protogalaxies) that are minimally as massive (or as
tightly bound) as our own Milky Way.
Compiled by
G.T.Petrov, 2004